Reflectance FTIR (Fourier Transform Infrared Spectra) of gemstones were acquired using a microscope IRscopeII (Bruker) accumulating 200 scans with a resolution of a cm-1 or better, in the range 7000-600 cm-1. Here are given only the skeletal bands which lie in the interval 1500-600 cm-1
When the samples were suitably cut in direction parallel or normal to the c axis, polarized spectra were also obtained on the pinacoid or on the basis respectively or both.
According to the group theory 6A2u + 16 E1u infrared modes are predicted: the E1u modes are observed in the spectrum when the electric field is perpendicular to the c-axis (ordinary ray) and the A2u modes are observed for the extraordinary ray (E|| c).
Therefore, non degenerate bands (A2u) are observed on pinacoids and show intensity changes in polarization, while degenerate bands (E1u) are detected on basis spectra and show only a lowering in intensity in polarized light.
Spectrum:
